Volla, Chandra M RaoVogel, Pierre2009-04-092009-04-092009-04-09200910.1021/ol9002509https://infoscience.epfl.ch/handle/20.500.14299/37065WOS:000265084300008FeCl2 catalyzes the oxidative C-C cross-coupling of tertiary amines with terminal alkynes into propargylamines using (t-BuO)2 as oxidant. The reaction can be applied to aromatic and aliphatic amines and alkynes without solvent. High chemoselectivity for aminomethyl groups is due to a steric factor.Molecular-OxygenHydrogen-PeroxideNitrogen AtomDirect ArylationAdjacentMetalWaterArylPropargylaminesCycloalkanesChemoselective C-H Bond Activation: Ligand and Solvent Free Iron-Catalyzed Oxidative C-C Cross-Coupling of Tertiary Amines with Terminal Alkynes. Reaction Scope and Mechanismtext::journal::journal article::research article