Kooij, BastiaanChen, Damien WenFadaei Tirani, FarzanehSeverin, Kay2024-08-022024-08-022024-08-012024-06-1010.1002/anie.202407945https://infoscience.epfl.ch/handle/20.500.14299/240542Carbodicarbenes are strong C‐donor ligands, which have found numerous applications in organometallic and main group element chemistry. Herein, we report a structurally distinct carbodicarbene ligand, which is formed by dinitrogenative coupling of a Fischer carbene complex with an N‐heterocyclic diazoolefin. The resulting carbonyl complex serves as a stable source for the mixed Arduengo‐Fischer carbodicarbene ligand. Facile ligand transfer reactions were demonstrated to occur with gold(I), copper(I), palladium(II), and rhodium(I) complexes.entext::journal::journal article::research article