Collisional energy transfer in the reactions I + NO + M -> INO + M and I + NO2 + M -> INO2 + M

Van den Bergh, H.Benoit-Guyot, N.Troe, J.2011-02-012011-02-012011-02-01197710.1002/kin.550090207https://infoscience.epfl.ch/handle/20.500.14299/63608The low-pressure recombination rate consts. of the reactions I + NO + M -> INO + M (with 14 different M) and I + NO2 + M -> INO2 + M (with 26 different M) were measured at 330 K by laser flash photolysis. The collision efficiencies bc are analyzed and compared with other thermal activation systems. Whereas bc increases in 1 reaction with an increasing no. of atoms in M, practically no such effect is found when, for the same M, different reactions with varying complexities of the reacting mols. are considered.10102-43-910102-44-0 Role: RCT (Reactant)RACT (Reactant or reagent) (recombination of iodine atom with3rd body effects on collisional energy transfer and kinetics of)14362-44-8 Role: RCT (Reactant)RACT (Reactant or reagent) (recombination ofiodine recombination nitrogen oxideenergy transfer recombination reactionCollisional energy transfer in the reactions I + NO + M -> INO + M and I + NO2 + M -> INO2 + Mtext::journal::journal article::research article