Gao, Hong-LingBi, Yan-XiaLi, Fang-FangCheung, Chi WaiWang, Wen-MinShen, Hai-YunCui, Jian-Zhong2015-09-282015-09-282015-09-28201510.1016/j.inoche.2015.05.001https://infoscience.epfl.ch/handle/20.500.14299/118864WOS:000358267800008Two new complexes based on pyridine-2,3,5,6-tetracarboxylic acid(H(4)pdtc) as ligand, {[Co-2(pdtc)(H2O)(4)]center dot H2O}(n) (1) and {Mn-2(pdtc)(H2O)(4)}(n) (2), have been obtained by hydrothermal syntheses and characterized by IR, elemental analysis, X-ray diffraction single crystal structure analysis, PXRD, thermal gravimetric analysis, and magnetic measurements. Complex 1 is 3D coordination polymer and complex 2 belongs to 2D grid structure by covalent bonds. In 1 and 2, the metal ions show antiferromagnetic interactions. (C) 2015 Elsevier B.V. All rights reserved.Pyridine polycarboxylic acidHydrothermal synthesis3D coordination polymerMagnetic propertySyntheses, structures and properties of cobalt and manganese complexes based on pyridine-2,3,5,6-tetracarboxylic acidtext::journal::journal article::research article