Cannizzo, Andreavan Mourik, FrankGawelda, WojciechZgrablic, GoranBressler, ChristianChergui, Majed2007-05-312007-05-312007-05-31200610.1002/anie.200600125https://infoscience.epfl.ch/handle/20.500.14299/7472WOS:0002375334000358617Femtosecond fluorescence-upconversion studies of aq. [Ru(bpy)3]2+ show a short-lived vibrationally hot emission of the singlet metal-to-ligand charge-transfer state, with an ultrafast intersystem crossing (~ 10 fs) to the triplet state at const. energy (the colors indicate the luminescence intensity). [on SciFinder (R)]Fluorescence up-conversion (broadband femtosecond fluorescence spectroscopy of [Ru(bpy)3]2+); Luminescence (hot; of [Ru(bpy)3]2+); Vibrational energy transfer (intramol.; of [Ru(bpy)3]2+); Intersystem crossing (of [Ru(bpy)3]2+); Intramolecular energy transfer (vibrational; of [Ru(bpy)3]2+)ruthenium complex bipyridine fluorescence hot upconversiontext::journal::journal article::research article