Laib, TaouesZhu, Jieping2010-11-252010-11-252010-11-25200010.1055/s-2000-7137https://infoscience.epfl.ch/handle/20.500.14299/58517An intramol. SNAr reaction was applied to the synthesis of a 13-membered meta-cyclophane that is the structural core of phomopsin and ustiloxin-type antimitotics. Two types of facile beta -elimination processes are also presented. [on SciFinder (R)]Cyclization (SNAr; prepn. of meta-cyclophane structural cores of antimitotic phomopsins and ustiloxins); Mitosis (antimitotic agents; prepn. of meta-cyclophane structural cores of antimitotic phomopsins and ustiloxins); Substitution reaction (arom.intramol. cyclization; prepn. of meta-cyclophane structural cores of antimitotic phomopsins and ustiloxins); Metacyclophanes Role: SPN (Synthetic preparation)PREP (Preparation) (prepn. of meta-cyclophane structural cores of antimitotic phomopsins and ustiloxins); Elimination reaction (beta -; prepn. of meta-cyclophane structural cores of antimitotic phomopsins and ustiloxins)phomopsin ustiloxin metacyclophane structural core prepntext::journal::journal article::research article