Shavaleev, Nail M.Scopelliti, RosarioBaranoff, EtienneGraetzel, MichaelNazeeruddin, Mohammad K.2012-03-222012-03-222012-03-22201210.1016/j.ica.2011.10.052https://infoscience.epfl.ch/handle/20.500.14299/78959WOS:000300623600047Bis-cyclometalated cationic Ir(III) diimine complexes [Ir((CN)-N-Lambda)2((NN)-N-Lambda)](PF6) with 1-phenylpyrazoles ((CN)-N-Lambda) and 1-(4'-tert-butyl-2'-pyridyl) pyrazole ((NN)-N-Lambda) are white solids that have absorption onset below 425 nm and electrochemical gap of up to 3.5 V. (C) 2011 Elsevier B. V. All rights reserved.IridiumCyclometalationComplexPyrazoleElectrochemistryIr(Iii) ComplexesLigandsBluePhosphorescentLightBlockingPyrazolesCharged cyclometalated iridium(III) complexes that have large electrochemical gaptext::journal::journal article::research article