Jedraszko, JustynaNogala, WojciechAdamiak, WojciechGirault, Hubert H.Opallo, Marcin2014-03-192014-03-192014-03-19201410.1016/j.elecom.2014.03.006https://infoscience.epfl.ch/handle/20.500.14299/102035WOS:000337555700006Scanning electrochemical microscopy potentiometric determination of local hydrogen concentration and its flux next to the liquid|liquid interface was demonstrated. This method is based on the shift of open circuit potential of Pt-based reversible hydrogen electrode. The detection system was verified with a system generating hydrogen under galvanostatic conditions. Then, it was applied to aqueous|1,2-dichloroethane interface where hydrogen is produced with decamethylferrocene as electron donor.Hydrogen potentiometric sensorHydrogen evolution reaction (HER)Liquid-liquidDecamethylferroceneScanning electrochemical microscopy (SECM)Reversible hydrogen electrode (RHE)Scanning electrochemical microscopy determination of hydrogen flux at liquid|liquid interface with potentiometric probetext::journal::journal article::research article