Dufour, JeremyNeuville, LucZhu, Jieping2010-11-252010-11-252010-11-25200810.1055/s-2008-1078209https://infoscience.epfl.ch/handle/20.500.14299/58419A concise total synthesis of arylomycin A2 was accomplished featuring a key intramol. Suzuki-Miyaura reaction for the formation of the 14-membered meta,meta-cyclophane and direct coupling of a fully elaborated peptide side-chain with the macrocyclic core. [on SciFinder (R)]Suzuki coupling reaction (intramol.Suzuki-Miyaura; total synthesis of signal peptidase I inhibitor arylomycin A2 via intramol. Suzuki-Miyaura reaction); Macrocyclization (total synthesis of signal peptidase I inhibitor arylomycin A2 via intramol. Suzuki-Miyaura reaction)arylomycin A2 signal peptidase I inhibitor total synthesis; tripeptide prepn intramol Suzuki Miyaura macrocyclizationTotal synthesis of arylomycin A2, a signal peptidase I (SPase I) inhibitortext::journal::journal article::research article