Highly Stereoselective Synthesis of (+/-)-Aminobromocyclitol Derivatives from Furan

Reynard, E.Reymond, J. L.Vogel, P.2005-11-092005-11-092005-11-09199110.1055/s-1991-20763https://infoscience.epfl.ch/handle/20.500.14299/219649The Diels-Alder adduct (2-cyano-7-oxabicyclo[2.2.1]-hept-5-en-2-yl acetate) of furan and 1-cyanovinyl acetate was converted to N-[(1RS,2RS,3RS,4SR,6RS)-2,3,4-triacetoxy-6-bromocyclohex-1-yl]benzamide and to N-[(1RS,2RS,3SR,4RS,5SR,6SR)-2,3,4,5-tetraacetoxy-6-bromocyclohex-1-yl]b enzamide with high stereoselectivity.Diels-alder reactionpseudo-sugarsnaked sugarshygromycin-aacidsmethoxyhygromycinaminocyclitolsvalienamineantibioticsinhibitorsHighly Stereoselective Synthesis of (+/-)-Aminobromocyclitol Derivatives from Furantext::journal::journal article::research article