High-Quality 2D Metal−Organic Coordination Network Providing Giant Cavities within Mesoscale Domains

KüHne, DirkKlappenberger, FlorianDecker, RéGisSchlickum, UtaBrune, HaraldKlyatskaya, SvetlanaRuben, MarioBarth, Johannes V.2010-03-252010-03-252010-03-25200910.1021/ja809946zhttps://infoscience.epfl.ch/handle/20.500.14299/48871WOS:000264792700043A surface-supported open metal−organic nanomesh featuring a 24 nm2 cavity size and extending to μm domains was fabricated by Co-directed assembly of para-hexaphenyl-dicarbonitrile linker molecules in two dimensions. The metallosupramolecular lattice is thermally robust and resides fully commensurate on the employed Ag(111) substrate as directly verified by high-resolution scanning tunneling microscopy observations.Supramolecular Architecture at SurfacesHigh-Quality 2D Metal−Organic Coordination Network Providing Giant Cavities within Mesoscale Domainstext::journal::journal article::research article