Jia, YanxingBois-Choussy, MicheleZhu, Jieping2010-11-252010-11-252010-11-25200710.1021/ol070889phttps://infoscience.epfl.ch/handle/20.500.14299/58434Palladium-catalyzed intramol. Suzuki-Miyaura reaction of linear tripeptide afforded the 16-membered DEFG ring of complestatin I in good yield with an excellent atropdiastereoselectivity. Acidic treatment of I triggers a stereospecific rearrangement leading to the corresponding DEFG ring II of chloropeptin I. [on SciFinder (R)]Suzuki coupling reaction (intramol.; stereoselective prepn. of fragments of complestatin and chloropeptin I starting from nitroaniline and dihydroxy(iodo)benzaldehyde using heterocyclizationasym. dihydroxylationand intramol. Suzuki-Miyaura reaction as key steps); Heterocyclization; Macrocyclization; Stereoselective synthesis (stereoselective prepn. of fragments of complestatin and chloropeptin I starting from nitroaniline and dihydroxy(iodo)benzaldehyde using heterocyclizationasym. dihydroxylationand intramol. Suzuki-Miyaura reaction as key steps); Cyclic peptides Role: SPN (Synthetic preparation)PREP (Preparation) (stereoselective prepn. of fragments of complestatin and chloropeptin I starting from nitroaniline and dihydroxy(iodo)benzaldehyde using heterocyclizationasym. dihydroxylationand intramol. Suzuki-Miyaura reaction as key steps); Dihydroxylation (stereoselective; stereoselective prepn. of fragments of complestatin and chloropeptin I starting from nitroaniline and dihydroxy(iodo)benzaldehyde using heterocyclizationasym. dihydroxylationand intramol. Suzuki-Miyaura reaction as key steps)complestatin chloropeptin I cyclotripeptide fragment asym prepntext::journal::journal article::research article