Phillips, ADLaurenczy, GScopelliti, RDyson, PJ2007-03-302007-03-302007-03-30200710.1021/om070017rhttps://infoscience.epfl.ch/handle/20.500.14299/4138WOS:00024424890000210177Formation of a vacant coordination site on a Ru center permits an unusual binding of small molecules such as ethylene, acetylene, and dihydrogen, resulting in the transformation of the chelating β-diketiminate ligand to a β-diimine. These representative species are observed during the catalytic hydrogenation of styrene.Facile, thermo-reversible cycloaddition of small molecules to a ruthenium(II) arene-diketiminatetext::journal::journal article::research article