Bakhvalova, Elena S.Bykov, Alexey V.Markova, Mariia E.Lugovoy, Yury V.Sidorov, Alexander I.Molchanov, Vladimir P.Sulman, Mikhail G.Kiwi-Minsker, LioubovNikoshvili, Linda Z.2023-07-312023-07-312023-07-312023-07-0110.3390/molecules28134938https://infoscience.epfl.ch/handle/20.500.14299/199489WOS:001028378200001In this work, for the first time, naphthalene (NA)-based polymers were synthesized by one-stage Friedel-Crafts crosslinking. The influence of NA functionalization by -OH, -SO3H, and -NO2 groups on the polymers' porosity and distribution of the catalytically active phase (Pd) was studied. Synthesized catalytic systems containing 1 wt.% of Pd either in the form of Pd(II) species or Pd(0) nanoparticles supported on NA-based polymers were tested in a model reaction of Suzuki cross-coupling between 4-bromoanisole and phenylboronic acid under mild reaction conditions (60 & DEG;C, ethanol-water mixture as a solvent). These novel catalysts demonstrated high efficiency with more than 95% of 4-bromoanisole conversion and high selectivity (>97%) for the target 4-methoxybiphenyl.Biochemistry & Molecular BiologyChemistry, MultidisciplinaryBiochemistry & Molecular BiologyChemistrynaphthalenefriedel-crafts crosslinkingsulfonationnitrationpalladiumsuzuki cross-couplinghypercrosslinked polystyreneselective hydrogenationmicroporous polymerslinked polymernanoparticlesperformancesulfonationpalladiumacidtext::journal::journal article::research article