Purins, MikusEichenberger, LucasWaser, Jerome2023-06-192023-06-192023-06-192023-05-3110.1039/d3cc01847dhttps://infoscience.epfl.ch/handle/20.500.14299/198307WOS:001000508900001Herein we report a mild synthesis of propargyl silanes from terminal alkynes. We exploit a bromonaphthyl-substituted silane as a silylmethyl electrophile surrogate, which participates in a Sonogashira reaction after an aryl-to-alkyl Pd-migration. Twenty-seven propargyl silanes were obtained in up to 88% yield. The obtained products were versatile building blocks that can be used in addition to electrophiles, triple bond hydrogenation or silyl group cleavage with acid or fluoride sources.Chemistry, MultidisciplinaryChemistrytext::journal::journal article::research article