Malakhov, MikhailCistaro, Giovanni ConsalvoMartin, FernandoPicon, Antonio2024-07-032024-07-032024-07-032024-06-1810.1038/s42005-024-01689-4https://infoscience.epfl.ch/handle/20.500.14299/209137WOS:001250887500001Excitons play an essential role in the optical response of two-dimensional materials. These are bound states showing up in the band gaps of many-body systems and are conceived as quasiparticles formed by an electron and a hole. By performing real-time simulations in hBN, we show that an ultrashort (few-fs) UV pulse can produce a coherent superposition of excitonic states that induces an oscillatory motion of electrons and holes between different valleys in reciprocal space, leading to a sizeable exciton migration in real space. We also show that an ultrafast spectroscopy scheme based on the absorption of an attosecond pulse in combination with the UV pulse can be used to read out the laser-induced coherences, hence to extract the characteristic time for exciton migration. This work opens the door towards ultrafast electronics and valleytronics adding time as a control knob and exploiting electron coherence at the early times of excitation.|Charge migration is one of the key applications of attosecond science mainly studied in molecular systems. Here the authors propose the extension of this process to two-dimensional materials by exploiting the excitonic interactions typical on these systems, performing numerical simulations to demonstrate the possibility to produce and read exciton migration in monolayer hBN.Physical SciencesAttosecondDynamicstext::journal::journal article::research article