Chen, GuihuaCao, JianWang, QianZhu, Jieping2020-01-242020-01-242020-01-24202010.1021/acs.orglett.9b04357https://infoscience.epfl.ch/handle/20.500.14299/164901In the presence of a catalytic amount of Pd(TFA)2 and a chiral Pyox ligand under oxygen atmosphere, oxidative Heck reaction between arylboronic acids and 4- substituted or 4,4-disubstituted cyclopent-1-enes afforded the chiral arylated products with concurrent creation of two stereocenters in good yields with excellent diastereo- and enantioselectivities.text::journal::journal article::research article