Olaya, Astrid J.Schaming, DelphineBrevet, Pierre-FrancoisNagatani, HirohisaXu, Hai-JunMeyer, MichelGirault, Hubert H.2012-07-132012-07-132012-07-13201210.1002/anie.201202266https://infoscience.epfl.ch/handle/20.500.14299/83855WOS:000305554500029Meet at the border: Assembly of the water-soluble cobalt tetrakis(N-methylpyridinium-4-yl)porphyrin [CoTMPyP]4+ at soft interfaces is enhanced and stabilized by its interfacial interaction with the lipophilic anion (C6F5)4B−. The supramolecular structure thus formed (see picture) provides excellent catalytic activity in the four-electron reduction of oxygen.interfacesliquid-liquid interfacesoxygen reduction reactionporphyrinsself-assemblyImmiscible Electrolyte-SolutionsMolecular Electrocatalysis2Nd-Harmonic GenerationPolarized InterfaceTetrathiafulvaleneAggregationDioxygenInterfacial Self-Assembly of Water-Soluble Cationic Porphyrins for the Reduction of Oxygen to Watertext::journal::journal article::research article