Alcoholate Clusters ("Aggregates") and Their Role in Alkyne Forming Elimination Reactions

Schlosser, ManfredTran Dinh, An2006-03-032006-03-032006-03-03198110.1002/anie.198110391https://infoscience.epfl.ch/handle/20.500.14299/226798Kinetic data for the dehydrochlorination of (E)- and (Z)-MeCH:CClC.tplbond.CCMe3 by KOCMe3 (I) in different solvents suggested that I assocs. participated in a push-pull, conveyor-belt mechanism. MeC.tplbond.CC.tplbond.CCMe3 was the only product from both olefin isomers. [on SciFinder (R)]Kinetics of dehydrochlorination (of chlorodimethylheptenyne by tert-butoxide); Dehydrochlorination (of chlorodimethylheptenyne by tert-butoxidebase aggregation in)dehydrochlorination chlorodimethylheptenyne butoxide aggregate; heptenyne chlorodimethyl dehydrochlorination butoxide aggregateAlcoholate Clusters ("Aggregates") and Their Role in Alkyne Forming Elimination Reactionstext::journal::journal article::research article