Winter, PhilippVaxelaire, CarineHeinz, ChristophChristmann, Mathias2015-09-012015-09-012015-09-01201110.1039/C0CC02332Ahttps://infoscience.epfl.ch/handle/20.500.14299/117508WOS:000285068300085The Cu-catalyzed synthesis of skipped 1,4-dienes from allylic acetates and vinyl-Grignard reagents is key to bidirectional modifications of acyclic terpene acetates. As a result, trisubstituted double bond containing subunits can be readily transferred into complex polyketides from inexpensive bulk terpenes.text::journal::journal article::research article