Tandem Pauson-Khand Reaction Using Carbon Dioxide as the C1-Source

Shyshkanov, SerhiiVasilyev, Dmitry V.Abhyankar, Kedar A.Stylianou, Kyriakos C.Dyson, Paul J.2022-07-042022-07-042022-07-042022-05-3110.1002/ejic.202200037https://infoscience.epfl.ch/handle/20.500.14299/188905WOS:000803081200001We describe the use of CO2 as a promising C1 source instead of CO in the tandem Pauson-Khand reaction. The reaction is achieved by combining the reduction of CO2 to CO using a metal organic framework (MOF) catalyst with homogeneous rhodium catalysts for the cycloaddition step. A range of substrates were converted in moderate to good yields.Chemistry, Inorganic & NuclearChemistryactivation of carbon dioxidecarbon dioxide reductioncascade processmetal organic frameworkspauson-khand reactionshape selectivitycarbonylationco2catalysisaldehydeshydroformylationmonoxidealkenesformatehalidesTandem Pauson-Khand Reaction Using Carbon Dioxide as the C1-Sourcetext::journal::journal article::research article