Louis, B.Tezel, C.Kiwi-Minsker, L.Renken, A.2006-04-182006-04-182006-04-18200110.1016/S0920-5861(01)00393-5https://infoscience.epfl.ch/handle/20.500.14299/229484Structured filamentous zeolitic materials were prepd. by depositing ZSM-5 coatings on glass fiber supports. A homogeneous coverage of the support filaments was obtained by prepg. MFI crystals in F-contg. media at neutral pH. The samples were characterized by BET, XRD and SEM. The gas-phase partial oxidn. of benzene by N2O to phenol was investigated as a function of the chem. compn. of the support and the ZSM-5 synthesis procedure. The fluorinated zeolitic materials demonstrated the highest activity (>20% benzene conversion) with 97% selectivity to phenol. [on SciFinder (R)]Oxidation catalysts (benzene oxidn. to phenol over ZSM-5-coated glass fiber catalysts); Glass fibers; Zeolite ZSM-5 Role: CAT (Catalyst use)USES (Uses) (benzene oxidn. to phenol over ZSM-5-coated glass fiber catalysts)benzene oxidn filamentous zeolite catalyst; phenol prepn benzene oxidn catalystCoatingsZSM-5Glass fibersStructured catalystBenzene hydroxylationN2OFluorine mediatext::journal::journal article::research article