New insights into the acid mediated disproportionation of pentavalent uranyl

Mougel, VictorBiswas, BiplabPecaut, JacquesMazzanti, Marinella2014-11-072014-11-072014-11-07201010.1039/c0cc03443fhttps://infoscience.epfl.ch/handle/20.500.14299/108485WOS:000284068100041The reaction of benzoic acid with the uranyl(v) complex [(UO 2Py5)(KI2Py2)] in pyridine leads to immediate disproportionation with formation of a hexanuclear U(iv) benzoate cluster, a bis-benzoate complex of uranyl(vi) and water. © 2010 The Royal Society of Chemistry.New insights into the acid mediated disproportionation of pentavalent uranyltext::journal::journal article::research article