Steel, Patrick G.Woods, Tom M.2010-11-302010-11-302010-11-30200910.1055/s-0029-1217067https://infoscience.epfl.ch/handle/20.500.14299/59560WOS:000272455100024Enol phosphinates and phosphonates can be readily prepared from simple lactams in high yields and are both stable and storable. Both these substrates can be employed successfully in homogeneous Suzuki-Miyaura and Stille cross-couplings protocols. Additionally, the phosphonate group can be immobilised on a phenol-on-polystyrene resin and utilised in a simple diversity linker strategy in which the coupled product is cleaved from the resin under Suzuki-Miyaura cross-coupling conditions.lactamsarylboronic acidsstannanesSuzuki-Miyaura couplingStille couplingresin-bound enol phosphinateNitrogen-Containing HeterocyclesHeteroaryl Boronic AcidsVinyl PhosphatesArylEfficientReagentsLactamstext::journal::journal article::research article