Mougel, VictorPecaut, JacquesMazzanti, Marinella2014-11-072014-11-072014-11-07201210.1039/c1cc16646hhttps://infoscience.epfl.ch/handle/20.500.14299/108491WOS:000299589700025U(iv) promotes the disproportionation of otherwise stable uranyl(v) Schiff base complexes affording U(iv)-U(v) oxo clusters with new geometries and the first example of a U(iv)⋯UO 2 + cation-cation interaction.New polynuclear U(IV)-U(V) complexes from U(IV) mediated uranyl(V) disproportionationtext::journal::journal article::research article