Mechanistic in situ high-pressure NMR studies of benzene hydrogenation by supramolecular cluster catalysis with [(eta(6)-C6H6)(eta(6)-C6Me6)(2)Ru-3(mu(3)-O)(mu(2)-OH)(mu(2)-H)(2)][BF4]

Laurenczy, GFaure, MVieille-Petit, LSuss-Fink, GWard, TR2005-11-092005-11-092005-11-09200210.1002/1615-4169(200212)344:10<1073::AID-ADSC1073>3.0.CO;2-Jhttps://infoscience.epfl.ch/handle/20.500.14299/219866WOS:0001800789000063750In situ high-pressure NMR spectroscopy of the hydrogenation of benzene to give cyclohexane, catalysed by the cluster cation [(eta(6)-C6H6) (eta(6)-C6Me6)(2)Ru-3(mu(3)-O)(mu(2)-OH)(mu(2)-H)(2)](+) 2, supports a mechanism involving a supramolecular host-guest complex of the substrate molecule in the hydrophobic pocket of the intact cluster molecule.aqueous-solutioncomplexesexchangeactivationMechanistic in situ high-pressure NMR studies of benzene hydrogenation by supramolecular cluster catalysis with [(eta(6)-C6H6)(eta(6)-C6Me6)(2)Ru-3(mu(3)-O)(mu(2)-OH)(mu(2)-H)(2)][BF4]text::journal::journal article::research article