Experimental determination of the oscillator strength of the 2160 A band of the free methyl radical and a spectroscopic measurement of the combination rate

Van den Bergh, H. E.Callear, A. B.Norstrom, R. J.2011-02-012011-02-012011-02-01196910.1016/0009-2614(69)85080-3https://infoscience.epfl.ch/handle/20.500.14299/63597The f-value of the 2160-.ANG. band of the free Me radical was detd. exptl. as (1.2 +- 0.2) * 10-2. The rate coeff. for combination is (2.43 +- 0.24) * 1013 cm3/mole-sec at 293 DegK. Me radicals were generated by the flash photolysis of small partial pressures of both Me2Hg and azomethane with Ar added to 100 torr in all expts.2229-07-4 Role: PRP (Properties) (spectrum ofoscillator strength bands in)combination rate Me radicalsoscillator strength Me radicalsUV free Me radicalsradicals Me free UVmethyl free radicals UVExperimental determination of the oscillator strength of the 2160 A band of the free methyl radical and a spectroscopic measurement of the combination ratetext::journal::journal article::research article