Masson, GeraldineHousseman, ChristopherZhu, Jieping2010-11-252010-11-252010-11-25200710.1002/anie.200604366https://infoscience.epfl.ch/handle/20.500.14299/58433This review summarizes recent mechanistic insights and advances in the design and synthesis of small org. mol. catalysts for enantioselective MBH and aza-MBH reactions. [on SciFinder (R)]Baylis-Hillman reaction (Morita-; review on mechanistic insights and advances in the design and synthesis of small org. mol. catalysts for enantioselective MBH and aza-MBH reactions); Lewis acids Role: CAT (Catalyst use)USES (Uses) (chiralorgano-; review on mechanistic insights and advances in the design and synthesis of small org. mol. catalysts for enantioselective MBH and aza-MBH reactions); Lewis bases Role: CAT (Catalyst use)USES (Uses) (organochiral; review on mechanistic insights and advances in the design and synthesis of small org. mol. catalysts for enantioselective MBH and aza-MBH reactions); Bronsted acids Role: CAT (Catalyst use)USES (Uses) (organo-chiral; review on mechanistic insights and advances in the design and synthesis of small org. mol. catalysts for enantioselective MBH and aza-MBH reactions); Ionic liquids (organo-; review on mechanistic insights and advances in the design and synthesis of small org. mol. catalysts for enantioselective MBH and aza-MBH reactions); Reaction mechanism; Stereoselective synthesis (review on mechanistic insights and advances in the design and synthesis of small org. mol. catalysts for enantioselective MBH and aza-MBH reactions); Amino acids; Phosphines Role: CAT (Catalyst use)USES (Uses) (review on mechanistic insights and advances in the design and synthesis of small org. mol. catalysts for enantioselective MBH and aza-MBH reactions); Addition reaction; Addition reaction catalysts (stereoselectiveMBH-aza-MBH-; review on mechanistic insights and advances in the design and synthesis of small org. mol. catalysts for enantioselective MBH and aza-MBH reactions); Amines Role: CAT (Catalyst use)USES (Uses) (tertiaryorganochiral; review on mechanistic insights and advances in the design and synthesis of small org. mol. catalysts for enantioselective MBH and aza-MBH reactions)review Morita Baylis Hillman aza mechanism enantioselective organo catalystThe enantioselective Morita-Baylis-Hillman reaction and its aza counterparttext::journal::journal article::research article