Nitrogen-doped graphene stabilized copper nanoparticles for Huisgen [3+2] cycloaddition "click" chemistry

Sanka, R. V. Siva PrasannaBalaji, K.Leterrier, YvesPandey, ShyamSrivastava, MonikaSrivastava, AnuragBinder, Wolfgang H.Rana, SravendraMichaud, Veronique2019-06-182019-06-182019-06-182019-06-0410.1039/c9cc02057hhttps://infoscience.epfl.ch/handle/20.500.14299/157722WOS:000469258900019Nitrogen-doped reduced graphene oxide (NRGO) stabilized copper nanoparticles are designed to assist Cu(I)-catalyzed Huisgen [3+2] cycloaddition "click" chemistry (CuAAC). This study demonstrates a robust route for the synthesis of vastly dispersed heterogeneous catalysts (NRGO/Cu2O), achieving CuAAC at low temperaturewithout any external additive (oxidizing/reducing agent) with high stability and recyclability. Underlying mechanisms are analysed using DFT calculations, confirming the experimental results.Chemistry, MultidisciplinaryChemistrycatalystNitrogen-doped graphene stabilized copper nanoparticles for Huisgen [3+2] cycloaddition "click" chemistrytext::journal::journal article::research article