Giraldi, EricaScopelliti, RosarioFadaei-Tirani, FarzanehSeverin, Kay2021-07-232021-07-232021-07-23202110.1021/acs.inorgchem.1c01719https://infoscience.epfl.ch/handle/20.500.14299/180173Molecular cages with arylboronate ester caps at the vertices are described. The cages were obtained by metal-templated polycondensation reactions of a tris(2-formylpyridine oxime) ligand with arylboronic acids. Suited templates are triflate or triflimide salts of ZnII, FeII, CoII, or MnII. In the products, the metal ions are coordinated internally to the pyridyl and oximato N atoms adjacent to the boronate ester, resulting in an improved hydrolytic stability of the latter. It is possible to decorate the cages with cyano or aldehyde groups using functionalized arylboronic acids. The aldehyde groups allow for a postsynthetic modification of the cages via an imine bond formation.text::journal::journal article::research article