Mantelis, CharalamposLavanchy, FredericMeyer, Thierry2009-02-092009-02-092009-02-092005https://infoscience.epfl.ch/handle/20.500.14299/34832Supercrit. fluids (SCFs) were intensively studied in the last decade as alternative, environment-friendly benign reaction solvents. A new anal. technique was derived from a combination of classical heat flow reaction calorimetry and the supercrit. fluid technol., namely supercrit. reaction calorimetry. When using SCFs, the internal heat-transfer coeff. decreases with increasing temp. Thus, there is a distinct limit to the heat that can be dissipated. A compromise must be made between a high reaction temp., where the reaction is faster but less safe, and a low reaction temp., where the reaction is slower but within safety limits in terms of heat removal.Calorimetry (reactionsupercrit. reaction calorimetry as route to supercrit. fluid reaction monitoring)Heat transferReactionSupercritical fluids (supercrit. reaction calorimetry as route to supercrit. fluid reaction monitoring)reaction calorimetry supercrit fluid reaction monitoringsafety supercrit reaction calorimetrytext::conference output::conference proceedings::conference paper