Jacobsen, Eric N.Chavez, David E.Gademann, Karl2006-11-222006-11-222006-11-222002https://infoscience.epfl.ch/handle/20.500.14299/235830A highly enantioselective and diastereoselective inverse electron demand hetero-Diels-Alder reaction between a variety of alpha,beta-unsatd. aldehydes and Et vinyl ether is described. The reaction is catalyzed by a chiral tridentate chromium(III) Schiff base complex, which is obtained by a concise and highly efficient protocol in two steps from com. materials. The resulting cycloadducts are isolated in good yields and are useful synthetic intermediates. [on SciFinder (R)]text::conference output::conference proceedings::conference paper