Xu, MingfeiWenger, SophieBala, HariShi, DongLi, RenzhiZhou, YanzhouZakeerudding, Shaik M.Grätzel, MichaelWang, Peng2009-10-122009-10-122009-10-12200910.1021/jp809319xhttps://infoscience.epfl.ch/handle/20.500.14299/43659WOS:000263299600045Cost-effective organic sensitizers will play a pivotal role in the future large-scale production and application of dye-sensitized solar cells. Here we report two new organic D-π-A dyes featuring electron-rich 3,4-ethylenedioxythiophene- and 2,2′-bis(3,4-ethylenedioxythiophene)-conjugated linkers, showing a remarkable red-shifting of photocurrent action spectra compared with their thiophene and bithiophene counterparts. On the basis of the 3-{5′-[N,N-bis(9,9-dimethylfluorene-2-yl)phenyl]-2,2′-bis(3,4-ethylenedioxythiophene)-5-yl}-2-cyanoacrylic acid dye, we have set a new efficiency record of 7.6% for solvent-free dye-sensitized solar cells based on metal-free organic sensitizers. Importantly, the cell exhibits an excellent stability, keeping over 92% of its initial efficiency after 1000 h accelerated tests under full sunlight soaking at 60 °C. This achievement will considerably encourage further design and exploration of metal-free organic dyes for higher performance dye-sensitized solar cells. We have also scrutinized the physical origins of the relatively low photocurrent and photovoltage obtained with an ionic liquid electrolyte compared to a volatile acetonitrile-based electrolyte through transient and modulated photoelectrical measurements.Efficient Molecular PhotovoltaicsIntensity-Modulated PhotovoltageIonic Liquid ElectrolytesSet Model ChemistryBand-Edge MovementCharge-TransportPhotocurrent SpectroscopyRuthenium SensitizersCo-SensitizationBack-Reactiontext::journal::journal article::research article