A versatile route to homo- and hetero-bimetallic 5f–5f and 3d–5f complexes supported by a redox active ligand framework

Camp, ClémentToniolo, DavideAndrez, JuliePécaut, JacquesMazzanti, Marinella2017-08-182018-09-142017-08-18201710.1039/C7DT01993Ahttps://infoscience.epfl.ch/handle/20.500.14299/139701WOS:000408697300003The salt-elimination reaction of the complex [Na2U(bis-salophen)] with metal halides provides an entry to the synthesis of well-defined homobimetallic uranium–uranium and rare heterobimetallic uranium–cobalt and uranium–nickel complexes supported by a redox-active dinucleating ligand.A versatile route to homo- and hetero-bimetallic 5f–5f and 3d–5f complexes supported by a redox active ligand frameworktext::journal::journal article::research article