Callear, Anthony B.Van den Bergh, H. E.2011-02-012011-02-012011-02-01197010.1016/0009-2614(70)80120-8https://infoscience.epfl.ch/handle/20.500.14299/63598In the flash photolysis of Me2Hg, approx. 85% of the Me radicals are produced in excited states. From a study of the relaxation rate in various gases, i.e. He, Ar, O2, it is evident that the free radicals are excited vibrationally and it is suggested that the rate is controlled by the out-of-plane bending mode. There was no dependence on pressure at >=3 torr for the combination of the Me radicals.2229-07-4P Role: FORM (Formationnonpreparative)PREP (Preparation) (formation ofin flash photolysis of dimethylmercury); 593-74-8 Role: RCT (Reactant)RACT (Reactant or reagent) (photolysis ofrelaxation of excited methyl radicals in)dimethyl mercury irradn; mercury dimethyl irradn; irradn dimethyl mercury; radicals dimethyl mercury irradn; excited radicals methyl; methyl radicalstext::journal::journal article::research article