Gautron, SLassauque, NLe Berre, CSerp, PAzam, LGiordano, RLaurenczy, GThiébaut, DKalck, P2006-03-302006-03-30200610.1002/ejic.200500931https://infoscience.epfl.ch/handle/20.500.14299/229043WOS:0002365087000028450High-pressure NMR mechanistic investigations into the promoting role of dicarbonyldiiodoplatinum complex in the iridium-catalysed carbonylation of methanol to acetic acid are consistent with iodide abstraction from the [IrI3(CH3)(CO)2]– resting state species by [PtI2(CO)2], unbolting the rate-limiting migratory CO insertion step. A new [Ir–Pt] heterodimetallic complex, which presumably represents the key species involved in the abstraction of I–, has been characterised by NMR in tandem with FAB-MS.text::journal::journal article::research article