Rabl, AkosRenken, Albert2006-04-182006-04-182006-04-18198610.1002/cite.330580524https://infoscience.epfl.ch/handle/20.500.14299/229349WOS:A1986C725100022The deactivation kinetics of catalysts for vinyl acetate (I) [108-05-4] manuf. from ethylene, AcOH, and O were studied in regard to product inhibition. Surface reactions were studied using models and a 2-parameter model was discussed which satisfactorily described the kinetics of relatively low I concns. I formation decreased with increasing CO2 and acetaldehyde [75-07-0] concns. The formation of I and CO2 occurred at different centers on the catalyst and followed different deactivation kinetics so the reactions could be selectively poisoned. [on SciFinder (R)]Catalysts and Catalysis (palladiumfor vinyl acetate manuf.deactivation kinetics in relation to)vinyl acetate manuf catalyst; deactivation kinetics catalyst vinyl acetatetext::journal::journal article::research article