Pedroni, J.Saget, T.Donets, P. A.Cramer, N.2015-09-282015-09-282015-09-28201510.1039/c5sc01909ehttps://infoscience.epfl.ch/handle/20.500.14299/119072WOS:000359214100009Taddol-based phosphoramidite ligands enable enantioselective palladium(0)-catalyzed C-H arylation of cyclopropanes. The cyclized products are obtained in high yields and enantioselectivities. The reported method provides efficient access to a broad range of synthetically attractive cyclopropyl containing dihydroquinolones and dihydroisoquinolones as well as allows for an efficient enantioselective construction of the 7-membered ring of the cyclopropyl indolobenzazepine core of BMS-791325.Enantioselective palladium(0)-catalyzed intramolecular cyclopropane functionalization: access to dihydroquinolones, dihydroisoquinolones and the BMS-791325 ring systemtext::journal::journal article::research article