Cross coupling of non-activated alkyl halides with alkynyl Grignard reagents catalyzed by a well-defined Ni pincer complex

Vechorkin, OlegGodinat, AurélienScopelliti, RosarioHu, Xile2011-09-242011-09-242011-09-24201110.1002/anie.201105964https://infoscience.epfl.ch/handle/20.500.14299/71089WOS:000298084900043The nickel pincer complex 1 catalyzes the cross-coupling of the title compounds with remarkable substrate scope and functional group tolerance. A nickel/alkynyl species was isolated and shown to be catalytically competent. THF=tetrahydrofuran, O-TMEDA=bis[2-(N,N-dimethylaminoethyl)] ether.enalkylationalkynescross-couplingGrignard reactionnickelCross coupling of non-activated alkyl halides with alkynyl Grignard reagents catalyzed by a well-defined Ni pincer complextext::journal::journal article::research article