Chapuis, Y.Yaouanc, A.de Reotier, P. DalmasMarin, C.Vanishri, S.Curnoe, S. H.Vaju, C.Forget, A.2011-12-162011-12-162011-12-16201010.1103/PhysRevB.82.100402https://infoscience.epfl.ch/handle/20.500.14299/75213WOS:000281486100001The magnetic entropy variation for the ordered spin-ice Tb2Sn2O7 and the spin-liquid Tb2Ti2O7 measured up to similar to 20 K shows that the crystal-field ground state for both systems is a singlet split from the first excited level by a thermal energy of similar to 2 K. It is the superexchange interactions between the Tb3+ spins which induce the terbium magnetic moments. Our results are analyzed in terms of a tetragonal perturbation for Tb2Ti2O7 and this perturbation plus a molecular field for Tb2Sn2O7.Antiferromagnet Tb2Ti2O7Spin IceEvidence from thermodynamic measurements for a singlet crystal-field ground state in pyrochlore Tb2Sn2O7 and Tb2Ti2O7text::journal::journal article::research article