Koestereli, ZiyaSeverin, Kay2015-02-202015-02-20201510.1039/c4ob02095bhttps://infoscience.epfl.ch/handle/20.500.14299/111284WOS:000345923800028An amphiphilic fluorescent dye with a disulfonated BODIPY head group and a heptadecyl side chain is described. In buffered aqueous solution, the amphiphile can form aggregates with a critical micelle concentration of similar to 20 mu M. The aggregation of the dye is associated with a strong quenching of its fluorescence. Al3+ promotes aggregation, whereas other metal ions have a much smaller effect, in particular when histidine is added as masking agent. The Al3+-induced aggregation can be used to sense Al3+ in the low micromolar concentration range with high selectivity. Furthermore, we demonstrate that a dye-Al3+ mixture can be used as a sensing ensemble for the detection of citric acid. The assay allows quantifying the citric acid content of commercial beverages such as energy drinks.text::journal::journal article::research article