An Iron Carbonyl Pyridonate Complex Related to the Active Site of the [Fe]-Hydrogenase (Hmd)

Obrist, Blaise V.Chen, DafaAhrens, AnneSchünemann, VolkerScopelliti, RosarioHu, Xile2009-03-202009-03-202009-03-20200910.1021/ic900281ghttps://infoscience.epfl.ch/handle/20.500.14299/36239WOS:000265166300023A mononuclear iron bis(carbonyl) pyridonate complex (1), which exhibits several common structural features with the active site of the iron−sulfur cluster-free [Fe]- hydrogenase, was synthesized and characterized. Spectroscopic data of 1 suggests a 2+ oxidation state for the Fe ion in the [Fe]-hydrogenase. Complex 1 serves as a precursor to other hydrogenase models.Cluster-Free HydrogenaseCrystal-StructureOnly HydrogenaseSulfur ProteinsModelCoordinationSpectroscopy2-PyridoneChemistryEvolutionAn Iron Carbonyl Pyridonate Complex Related to the Active Site of the [Fe]-Hydrogenase (Hmd)text::journal::journal article::research article