Duerr, HeinzBarth, DieterSchlosser, Manfred2006-03-032006-03-032006-03-03197410.1016/S0040-4039(01)91817-9https://infoscience.epfl.ch/handle/20.500.14299/226746Short-wavelength irradn. of Ph3P+C-Me2 gave C6H6 and a resinous compd. Long-wavelength irradn. of Ph3P+C-Me2 gave mainly Ph3P and Me2C:CMe2 with some Me2CHCHMe2, MeCH:CH2, and, with Me2CHCHMe2 as solvent, traces of (Me2CH)2CMe2 and Me2CHCHMeCH2CHMe2. the reaction proceeded via .CMe2.PPh3. [on SciFinder (R)]Photolysis (of triphenylphosphonium isopropylidemechanism); Ylides Role: PRP (Properties) (phosphorusphotolysis ofmechanism of)phosphorus ylide photochem decompntext::journal::journal article::research article