Carbonnelle, Anny-ClaudeZhu, Jieping2010-11-252010-11-252010-11-25200010.1021/ol006520ghttps://infoscience.epfl.ch/handle/20.500.14299/58519A novel macrocyclization procedure is developed on the basis of a domino process. Thus, treatment of linear diiodide I under defined conditions gave a 15-membered m,m-cyclophane via aryl-aryl bond formation. Two distinct cross-coupling manifolds, Miyaura's arylboronic ester synthesis and intramol. Suzuki reaction, proceed in an ordered fashion. Concn. is an important factor for the success of this process. [on SciFinder (R)]Suzuki coupling reaction (prepn. of biaryl-contg. macrocycles by a domino Miyaura arylboronate formation:intramol. Suzuki reaction)biphenomycin A model prepn; arylboronic ester prepn intramol Suzuki reactiontext::journal::journal article::research article