Intramolecular Heck-type Reactions in Aqueous Medium. A Dramatic Change in Regioselectivity
Lemaire-Audoire, Sandrine; Savignac, Monique; Dupuis, Christophe; Genêt, Jean-Pierre
1996

Abstract

Efficient intramolecular Heck-type cyclizations were carried out in aqueous medium using water-soluble Pd/TPPTS catalysts. Under these conditions, the generally observed exo process was reversed in favor of the regioselective formation of endo cyclized compounds.

Details

Title Intramolecular Heck-type Reactions in Aqueous Medium. A Dramatic Change in Regioselectivity
Author(s) Lemaire-Audoire, Sandrine ; Savignac, Monique ; Dupuis, Christophe ; Genêt, Jean-Pierre
Published in Tetrahedron Letters
Volume 37
Issue 12
Pages 2003-2006
Date 1996
Keywords
DOI https://doi.org/10.1016/0040-4039(96)00253-5
Laboratories LGSA
Record Appears in Scientific production and competences > SB - School of Basic Sciences > SB Archives > LGSA - Laboratory of Glycochemistry and Asymmetric Synthesis
Peer-reviewed publications
Work outside EPFL
Journal Articles
Published
Record creation date 2006-06-19

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