Intramolecular Heck-type Reactions in Aqueous Medium. A Dramatic Change in Regioselectivity

Efficient intramolecular Heck-type cyclizations were carried out in aqueous medium using water-soluble Pd/TPPTS catalysts. Under these conditions, the generally observed exo process was reversed in favor of the regioselective formation of endo cyclized compounds.


Published in:
Tetrahedron Letters, 37, 12, 2003-2006
Year:
1996
Keywords:
Laboratories:




 Record created 2006-06-19, last modified 2018-03-17


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