Selective Deprotection Method Using Palladium Water Soluble Catalysts
1994
Abstract
Allylcarboxy and Allyloxycarbonyl groups can be removed without affecting dimethylallylcarboxy and cinnamylcarboxy groups in the same molecule. using Pd(0) water soluble catalyst prepared in situ, with diethylamine as allyl scavenger. Homogeneous or biphasic media are suitable: the yields of deprotection are quantitative.
Details
Title
Selective Deprotection Method Using Palladium Water Soluble Catalysts
Author(s)
Lemaire-Audoire, Sandrine ; Blart, Erol ; Savignac, Monique ; Pourcelot, Guy ; Genêt, Jean-Pierre ; Bernard, Jean-Marie
Published in
Tetrahedron Letters
Volume
35
Issue
47
Pages
8783-8786
Date
1994
Laboratories
LGSA
Record Appears in
Scientific production and competences > SB - School of Basic Sciences > SB Archives > LGSA - Laboratory of Glycochemistry and Asymmetric Synthesis
Peer-reviewed publications
Work outside EPFL
Journal Articles
Published
Peer-reviewed publications
Work outside EPFL
Journal Articles
Published
Record creation date
2006-06-16