Smooth removal of the Allyloxycarbonyl (Alloc) moiety from allylic esters, carbamates and carbonates is carried out by Pd (O) catalyzed allyl transfer to diethylamine and thio derivatives as the accepting nucleophiles. The method has been successfully used for selective deprotection of secondary amines and base sensitive substrates.
Type
research article
Authors
Genêt, Jean Pierre
•
Blart, Erol
•
Savignac, Monique
•
Lemaire-Audoire, Sandrine
•
Bernard, Jean-Marie
Publication date
1993
Published in
Issue
9
Start page
680
End page
682
Peer reviewed
REVIEWED
EPFL units
Available on Infoscience
June 16, 2006
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