000084316 001__ 84316
000084316 005__ 20181203020406.0
000084316 0247_ $$2doi$$a10.1002/cite.330660413
000084316 037__ $$aARTICLE
000084316 245__ $$aReaction engineering studies on the copolymerization of styrene with maleic anhydride in a loop reactor
000084316 269__ $$a1994
000084316 260__ $$c1994
000084316 336__ $$aJournal Articles
000084316 500__ $$aCAN 121:135326, 37-3, Plastics Manufacture and Processing, Inst. Genie Chim.,Eidg. Tech. Hochsch. Lausanne,Lausanne,Switz., Journal, 0009-286X, written in German., 9011-13-6P (Maleic anhydride-styrene copolymer) Role: PREP (Preparation) (manuf. of, in loop reactor, chem. engineering study of)
000084316 520__ $$aThe heat-induced, solvent-free copolymn. of styrene (I) with maleic anhydride (II) was studied on a pilot scale in a loop reactor coupled to a tube reactor. Under conditions required for the manuf. of alternating copolymers (stoichiometric ratio of I to II or excess II) rapid reaction kinetics were obsd. resulting from the Trommsdorff effect, which, with the high reaction enthalpy of .apprx.80 kJ/mol. led to thermal instabilities esp. during start-up and at low recirculating rates. This was overcome by effective reactor control. The manuf. of products with low contents of II was also demonstrated possible by employing low II concns. (4-16%) in the monomer mixt. and rapid and efficient reactant mixing. [on SciFinder (R)]
000084316 6531_ $$aPolymerization (app.
000084316 6531_ $$aloop reactors
000084316 6531_ $$afor maleic anhydride with styrene)
000084316 6531_ $$amaleic anhydride styrene pilot polymn; loop reactor maleic styrene polymn
000084316 700__ $$aBelkhiria, Sahbi
000084316 700__ $$0241136$$g105841$$aMeyer, Thierry
000084316 700__ $$aRenken, Albert$$g106205$$0240078
000084316 773__ $$j66$$tChemie Ingenieur Technik$$k4$$q513-16
000084316 909C0 $$xU10177$$0252137$$pGSCP
000084316 909C0 $$xU10178$$0252033$$pLGRC
000084316 909CO $$pSB$$particle$$ooai:infoscience.tind.io:84316
000084316 917Z8 $$x148230
000084316 937__ $$aLGRC-ARTICLE-1994-007
000084316 970__ $$a182/LGRC
000084316 973__ $$rREVIEWED$$sPUBLISHED$$aEPFL
000084316 980__ $$aARTICLE