Journal article

Transient behavior of heterogeneous catalytic reactions with educt inhibition

Under periodic operating conditions, the instantaneous rate of the heterogeneous catalytic addn. of HOAc to ethylene can be an order of magnitude higher than at steady state. A real surface, multistep control model takes into account the strong inhibition of the acid to ethylene sorption and describes the steady state and transient behavior quant. [on SciFinder (R)]


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